The canton Vallon-Pont-d'Arc has 30 communes.
| Code | Name | Population ▼ |
|---|---|---|
| 07330 | Vallon-Pont-d'Arc | 2 403 |
| 07201 | Ruoms | 2 311 |
| 07132 | Largentière | 1 450 |
| 07126 | Lagorce | 1 257 |
| 07207 | Saint-Alban-Auriolles | 1 138 |
| 07134 | Laurac-en-Vivarais | 1 045 |
| 07348 | Vogüé | 1 040 |
| 07058 | Chassiers | 989 |
| 07101 | Grospierres | 941 |
| 07291 | Saint-Remèze | 847 |
| 07304 | Salavas | 740 |
| 07115 | Labeaume | 698 |
| 07328 | Vagnas | 636 |
| 07168 | Orgnac-l'Aven | 575 |
| 07162 | Montréal | 573 |
| 07183 | Pradons | 545 |
| 07307 | Sanilhac | 437 |
| 07061 | Chauzon | 422 |
| 07327 | Uzer | 421 |
| 07023 | Balazuc | 389 |
| 07272 | Saint-Maurice-d'Ardèche | 375 |
| 07109 | Joannas | 328 |
| 07113 | Labastide-de-Virac | 328 |
| 07193 | Rocher | 306 |
| 07306 | Sampzon | 241 |
| 07033 | Bessas | 234 |
| 07190 | Rochecolombe | 227 |
| 07318 | Tauriers | 203 |
| 07062 | Chazeaux | 134 |
| 07187 | Prunet | 134 |